Construction of eight mixed-valence pentanuclear CuI4Cu<sup>II</sup> clusters using ligands with inhomogeneous electron density distribution: synthesis, characterization and photothermal properties
Zi-Xuan Yao, Jingzhe Li, Hao-Hai Wang, Xun Cheng, Lin‐Lin Hou, Dong-Nan Yu, Delun Chen, Wenyan Dan, Kuan‐Guan Liu
Abstract
Eight mixed-valence pentanuclear CuI4Cu II clusters constructed by 1,2,3-triazole or tetrazole and different mono-phosphine ligands have been fabricated. They exhibit excellent photothermal conversion performance.
Topics & Concepts
Valence (chemistry)ChemistryIonPhotothermal therapyCopperCrystallographyAbsorption (acoustics)Analytical Chemistry (journal)Materials scienceNanotechnologyOrganic chemistryComposite materialCopper-based nanomaterials and applicationsAdvanced Photocatalysis TechniquesNanocluster Synthesis and Applications