High-pressure synthesis and crystal structures of molybdenum nitride Mo<sub>3</sub>N<sub>5</sub> with anisotropic compressibility by a nitrogen dimer
Takuya Sasaki, Takuro Yamamoto, Shuto Asano, Ken Niwa, Masashi Hasegawa
Abstract
Molybdenum nitride Mo 3 N 5 with higher coordinates of molybdenum sites and an N–N dimer was synthesized under a high pressure of above 45 GPa.
Topics & Concepts
Orthorhombic crystal systemDimerCompressibilityBulk modulusMolybdenumCrystallographyAnisotropyCrystal structureNitrideLattice constantDiamond anvil cellMaterials scienceEnthalpyPhase (matter)ChemistryThermodynamicsInorganic chemistryHigh pressureDiffractionNanotechnologyOrganic chemistryLayer (electronics)OpticsPhysicsComposite materialQuantum mechanicsMetal and Thin Film MechanicsBoron and Carbon Nanomaterials ResearchMXene and MAX Phase Materials