Synthesis, structure and reactivity of NO<sup>+</sup>, NO˙ and NO<sup>−</sup>pincer PCN-Rh complexes
Cecilia Mariel Gallego, Carina Gaviglio, Yehoshoa Ben‐David, David Milstein, Fabio Doctorovich, Juan Pellegrino
Abstract
Synthesis of a rhodium PCN pincer-type nitrosyl complex is described. Coordination to the metallic center by weakly coordinating anions was found, as well as a slight stabilization of higher oxidation states when compared to a PCP analogue.
Topics & Concepts
Pincer movementRhodiumReactivity (psychology)ChemistryCenter (category theory)MetalStereochemistryCrystallographyMedicinal chemistryCatalysisOrganic chemistryMedicinePathologyAlternative medicineMagnetism in coordination complexesInorganic Fluorides and Related CompoundsAdvanced Chemical Physics Studies