A new yttrium‐based metal–organic framework for molecular sieving of propane from propylene with high propylene capacity
Shi Tu, Liang Yu, Ying Wu, Yongwei Chen, Houxiao Wu, Liuqing Wang, Baoyu Liu, Xin Zhou, Jing Xiao, Qibin Xia
Abstract
Abstract Developing energy‐efficient alternatives for propylene (C 3 H 6 ) and propane (C 3 H 8 ) separation is of great significance and challenge in the petrochemical industry. Herein, we report the rational design of a new yttrium‐based ultramicroporous metal–organic framework (MOF) comprised of 12‐connected hexanuclear [Y 6 (OH) 8 (COO) 12 ] 2− cluster and 5‐(3,5‐dicarboxybenzoylamino)isophthalic acid (H 4 dbai) with ftw topology. It possesses a suitable pore window size and a relatively large pore volume for molecular sieving separation of C 3 H 8 from C 3 H 6 with a high C 3 H 6 capacity. At 298 K and 100 kPa, the adsorption capacity of C 3 H 6 was 2.57 mmol/g, which is the highest among the reported C 3 H 6 /C 3 H 8 molecular sieving MOF adsorbents. The molecular simulation revealed that the steric hindrance effect together with the electrostatic interaction of the oxygen sites in the window resulted in the molecular sieving separation of C 3 H 6 /C 3 H 8 . The breakthrough experiments confirmed its excellent separation performance under dynamic conditions to produce high purity (97.1%) of C 3 H 6 with a working adsorption capacity of 1.75 mmol/g.