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Altermagnetism, piezovalley, and ferroelectricity in two-dimensional Cr2SeO altermagnet

Imran Khan, Djamel Bezzerga, Brahim Marfoua, Jisang Hong

2025npj 2D Materials and Applications24 citationsDOIOpen Access PDF

Abstract

The study on altermagnet is receiving extensive research efforts due to its directional-dependent spin-polarized band structure. Here, we investigate the multifunctional properties of the Janus Cr 2 SeO monolayer system. The Cr 2 SeO monolayer exhibits an in-plane magnetic anisotropy energy of -0.28 meV/cell and a Neel temperature of around 280 K, which is further enhanced to 315 K under 1% uniaxial compressive strain. The Janus Cr 2 SeO exhibits spin band inversion with a large spin splitting of 0.38 eV at the Y and X high-symmetry points. Nonetheless, the valleys are degenerated due to the diagonal mirror symmetry. The uniaxial strain effectively breaks the diagonal mirror symmetry in the Janus Cr 2 SeO monolayer, and the strain-induced valley polarization of up to 90 meV is achieved. Furthermore, the uniaxial strain tunes the band gap between 0.30 eV to 0.76 eV. Moreover, Cr 2 SeO demonstrates ferroelectricity, with a total electric polarization of 5.34 pC/m, which increases to 5.52 pC/m under small uniaxial strain. Besides, we found a large vertical piezoelectric coefficient d 31 of 1.18 pm/V. Our study suggests that the Janus Cr 2 SeO is a promising platform for Valleytronics and ferroelectric memory applications at room temperature.

Topics & Concepts

FerroelectricityMaterials scienceGeologyOptoelectronicsDielectric2D Materials and ApplicationsMultiferroics and related materialsHeusler alloys: electronic and magnetic properties
Altermagnetism, piezovalley, and ferroelectricity in two-dimensional Cr2SeO altermagnet | Litcius