Free-standing metal–organic framework (MOF) monolayers by self-assembly of polymer-grafted nanoparticles
Kyle Barcus, Seth M. Cohen
Abstract
. Mixed-particle films were prepared through the assembly of MOF mixtures, while multilayer films were achieved through sequential transfer of the monolayers to a glass slide substrate. This method offers a modular and generalizable route to fabricate thin-films with inherent porosity and sub-micron thickness composed of a variety of MOF particles and functionalities.
Topics & Concepts
MonolayerMetal-organic frameworkNanoparticlePolymerSelf-assemblyMaterials scienceMetalOrganic polymerChemical engineeringNanotechnologyPolymer chemistryChemistryOrganic chemistryAdsorptionComposite materialMetallurgyEngineeringMetal-Organic Frameworks: Synthesis and ApplicationsDendrimers and Hyperbranched PolymersCovalent Organic Framework Applications