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Shape-adaptive single-molecule magnetism and hysteresis up to 14 K in oxide clusterfullerenes Dy<sub>2</sub>O@C<sub>72</sub> and Dy<sub>2</sub>O@C<sub>74</sub> with fused pentagon pairs and flexible Dy–(μ<sub>2</sub>-O)–Dy angle

Georgios Velkos, Wei Yang, Yang‐Rong Yao, Svetlana M. Sudarkova, XinYe Liu, B. Büchner, Stanislav M. Avdoshenko, Ning Chen, Alexey A. Popov

2020Chemical Science40 citationsDOIOpen Access PDF

Abstract

exhibits zero-field quantum tunneling of magnetization and magnetic hysteresis up to 14 K, the highest temperature among Dy-clusterfullerenes.

Topics & Concepts

MagnetismMagnetizationHysteresisDysprosiumRelaxation (psychology)Materials scienceOxideCrystallographyDipoleCondensed matter physicsChemistryNuclear magnetic resonancePhysicsInorganic chemistryMagnetic fieldMetallurgyPsychologySocial psychologyQuantum mechanicsOrganic chemistryMagnetism in coordination complexesFullerene Chemistry and ApplicationsGraphene research and applications
Shape-adaptive single-molecule magnetism and hysteresis up to 14 K in oxide clusterfullerenes Dy<sub>2</sub>O@C<sub>72</sub> and Dy<sub>2</sub>O@C<sub>74</sub> with fused pentagon pairs and flexible Dy–(μ<sub>2</sub>-O)–Dy angle | Litcius