Anomalous versus Normal Room-Temperature Diffusion of Metal Adatoms on Graphene

Abstract

domains during ∼0.04 ns timeframes, and they occasionally perform ∼2-4 nm flights across multiple surface adsorption sites. This anomalous diffusion pattern is associated with a flat (<50 meV) potential energy landscape (PEL), which renders surface vibrations important for adatom migration. The latter is not the case for Pt and Ru, which encounter a significantly rougher PEL (>100 meV) and, hence, migrate via conventional random walks. Thus, adatom anomalous diffusion is a potentially important aspect for modeling growth of metal films and nanostructures on 2D materials.

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