Experimental and Theoretical Study on the “2,2′-Bipiridyl-Ni-Catalyzed” Hirao Reaction of >P(O)H Reagents and Halobenzenes: A Ni(0) → Ni(II) or a Ni(II) → Ni(IV) Mechanism?

György Keglevich, Réka Henyecz, Zoltán Mucsi

2020The Journal of Organic Chemistry26 citationsDOI Open Access PDF

Abstract

-reagents were in accord with our mechanistic proposition.

Topics & Concepts

ChemistryReagentCatalysisDeprotonationLigand (biochemistry)BipyridineNickelMedicinal chemistry2,2'-BipyridineReaction mechanismOxidative additionIonInorganic chemistryCrystallographyPhysical chemistryOrganic chemistryCrystal structureReceptorBiochemistryCatalytic C–H Functionalization MethodsCatalytic Cross-Coupling ReactionsCyclopropane Reaction Mechanisms

Experimental and Theoretical Study on the “2,2′-Bipiridyl-Ni-Catalyzed” Hirao Reaction of &gt;P(O)H Reagents and Halobenzenes: A Ni(0) → Ni(II) or a Ni(II) → Ni(IV) Mechanism?

Abstract

Topics & Concepts

Experimental and Theoretical Study on the “2,2′-Bipiridyl-Ni-Catalyzed” Hirao Reaction of >P(O)H Reagents and Halobenzenes: A Ni(0) → Ni(II) or a Ni(II) → Ni(IV) Mechanism?