Access to disulfides through ligand-controlled nickel-catalyzed dithiosulfonate and alkyl halides
Wang Chen, Xinyu Liu, Daopeng Sheng, Yi‐Fan Jiang, Weidong Rao, Shusu Shen, Zhao‐Ying Yang, Shun‐Yi Wang
Abstract
Nickel-catalyzed C–SS reductive cross-coupling reaction of dithiosulfonate and unactivated alkyl halides for producing unsymmetric disulfides with broad substrate scope under mild conditions and with excellent functional group tolerance.
Topics & Concepts
ChemistryHalideAlkylNickelLigand (biochemistry)CatalysisSubstrate (aquarium)Functional groupCombinatorial chemistryCoupling reactionPolymer chemistryOrganic chemistryBiochemistryReceptorGeologyOceanographyPolymerSulfur-Based Synthesis TechniquesChemical Synthesis and ReactionsCatalytic Cross-Coupling Reactions