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K<sub>2</sub>S<sub>2</sub>O<sub>8</sub> promoted dehydrative cross-coupling between α,α-disubstituted allylic alcohols and thiophenols/thiols

Guozhe Guo, Yong Yuan, Shuocheng Wan, Xuehui Cao, Yali Sun, Congde Huo

2021Organic Chemistry Frontiers22 citationsDOI

Abstract

K<sub>2</sub>S<sub>2</sub>O<sub>8</sub> promoted dehydrative cross-coupling between α,α-disubstituted allylic alcohols and thiophenols/thiols is demonstrated for the first time, leading to a wide range of allyl sulfides in good to high yields.

Topics & Concepts

Allylic rearrangementChemistryCoupling (piping)Medicinal chemistryCatalysisOrganic chemistryMechanical engineeringEngineeringSulfur-Based Synthesis TechniquesChemical Synthesis and ReactionsSynthesis and Catalytic Reactions
K<sub>2</sub>S<sub>2</sub>O<sub>8</sub> promoted dehydrative cross-coupling between α,α-disubstituted allylic alcohols and thiophenols/thiols | Litcius