Hydrothermal Synthesis and Photocatalytic Property of Sn-doped β-Ga<sub>2</sub>O<sub>3</sub> Nanostructure
Heejoong Ryou, Tae Hee Yoo, Youngbin Yoon, In Gyu Lee, Myunghun Shin, Junsang Cho, Byung Jin Cho, Wan Sik Hwang
Abstract
Tin (Sn)-doped beta phase gallium oxide ( β -Ga 2 O 3 ) nanostructures at different Sn concentrations (0 to 7.3 at%) are synthesized using a facile hydrothermal method. The Sn-doped β -Ga 2 O 3 nanostructures are characterized using scanning electron microscopy, transmission electron microscopy, energy dispersive X-ray spectroscopy, X-ray powder diffraction, X-ray photoelectron spectroscopy, and absorbance spectroscopy. In addition, their photocatalytic activity is evaluated by observing methylene blue degradation under ultraviolet light (254 nm) irradiation. The photocatalytic activity of the Sn-doped (0.7 at%) β -Ga 2 O 3 nanostructures is significantly enhanced compared to that of intrinsic β -Ga 2 O 3 nanostructures due to the elevated charge separation. Excessive Sn concentrations (exceeding 2.2 at%) above the solid solubility limit of the Sn in β -Ga 2 O 3 nanostructures lead to SnO 2 and SnO precipitation. The presence of SnO 2 and SnO degrades the photocatalytic efficiency in the β -Ga 2 O 3 nanostructures. The results suggest new opportunities for the synthesis of highly effective β -Ga 2 O 3 -based photocatalysts for applications in environmental remediation, disinfection, and selective organic transformations.