Regio- and stereoselective divergent cross-coupling of alkynes and disubstituted alkenes <i>via</i> photoredox cobalt dual catalysis
Shiqi Zhang, Yan-Lin Li, Kun Cui, Chen Chen, Zheng‐Yang Gu, Hu He, Ji‐Bao Xia
Abstract
Regio- and stereoselective divergent cross-coupling of alkynes and gem-disubstituted alkenes has been reported by merging visible light photoredox and cobalt catalysis. The selective ene-type or reductive coupling reaction has been achieved by stwich of different ligands.
Topics & Concepts
ChemistryStereoselectivityCobaltCatalysisPhotoredox catalysisCoupling reactionCoupling (piping)Combinatorial chemistryAlkyneAlkenePhotochemistryOrganic chemistryPhotocatalysisEngineeringMechanical engineeringRadical Photochemical ReactionsCatalytic C–H Functionalization MethodsSulfur-Based Synthesis Techniques