Hidden Structural Evolution and Bond Valence Control in Near-Infrared Phosphors for Light-Emitting Diodes
Mu‐Huai Fang, Kuan‐Chun Chen, Natalia Majewska, Tadeusz Leśniewski, Sebastian Mahlik, Grzegorz Leniec, S.M. Kaczmarek, Chia‐Wei Yang, Kuang‐Mao Lu, Hwo‐Shuenn Sheu, Ru‐Shi Liu
Abstract
We aim to conduct a complete study on the unexpected structure evolution behavior in Cr3+-doped phosphors. A series of Ga2–xScxO3:Cr3+ phosphors are successfully synthesized and confirmed through structural studies, while the lattice parameters change unexpectedly. The unique partial substitution (∼87%) of Sc3+ in the octahedral site is demonstrated via Rietveld refinement. Therefore, the bond valence sum calculation explains the reason for this particular Sc3+ concentration. The photoluminescent bandwidth and electron–lattice coupling energy initially increase and then decrease, implying an inhomogeneous broadening effect. Time-resolved spectra and electron paramagnetic resonance are utilized to further examine the subtle change in the microstructures and the second coordination sphere effect of Cr3+. Ga1.594Sc0.4O3:0.006Cr3+ exhibits high internal quantum efficiency (99%) and high phosphor-converted light-emitting diode output power (66.09 mW), demonstrating its capability as an outstanding infrared phosphor. This work will motivate further research on unexpected partial substitution during the solid solution process.