Litcius/Paper detail

Visible-light-induced 1,3-difunctionalization of allylboronic esters enabled by a 1,2-boron shift

Panjie Xiang, Kai Sun, Anzai Shi, Jiangzhen An, Xiaolan Chen, Lingbo Qu, Bing Yu

2025Green Chemistry15 citationsDOI

Abstract

A novel visible-light-induced strategy has been developed for 1,2-boron migration to achieve 1,3-difunctionalization of allylboronic esters using vinyl triflates as bifunctional reagents.

Topics & Concepts

BoronBifunctionalReagentChemistryCombinatorial chemistryVisible spectrumPhotochemistryOrganic chemistryMaterials scienceCatalysisOptoelectronicsRadical Photochemical ReactionsCatalytic Cross-Coupling ReactionsSulfur-Based Synthesis Techniques