Tuning the photophysical properties of lanthanide(<scp>iii</scp>)/zinc(<scp>ii</scp>) ‘encapsulated sandwich’ metallacrowns emitting in the near-infrared range
Svetlana V. Eliseeva, Tu N. Nguyen, Jeff W. Kampf, Evan R. Trivedi, Vincent L. Pecoraro, Stéphane Pètoud
Abstract
We have created a family of ‘encapsulated sandwich’ Zn 16 Ln(HA) 16 metallacrowns and by detailed quantitative analysis demonstrated how the nature of the hydroximate ligand impacts photophysical properties of these complexes.
Topics & Concepts
LanthanideZincLigand (biochemistry)ChemistryInfraredReceptorOrganic chemistryBiochemistryPhysicsOpticsIonLanthanide and Transition Metal ComplexesMagnetism in coordination complexesNanocluster Synthesis and Applications