Non-directed C–H arylation of electron-deficient arenes by synergistic silver and Pd<sub>3</sub> cluster catalysis
Jian Yao, Jiahui Bai, Xi Kang, Manzhou Zhu, Yinlong Guo, Xiaoming Wang
Abstract
Cl) species as a catalyst precursor in Ag(I)-assisted direct C-H arylation with aryl iodides under mild conditions. This catalyst system leads to the formation of synthetically important biaryls in good yields with high site selectivities without the assistance of directing groups.
Topics & Concepts
CatalysisPalladiumArylTransition metalCluster (spacecraft)ChemistryCombinatorial chemistryReactivity (psychology)MetalSubstrate (aquarium)NanotechnologyMaterials scienceOrganic chemistryGeologyPathologyAlkylMedicineAlternative medicineProgramming languageComputer scienceOceanographyCatalytic C–H Functionalization MethodsNanocluster Synthesis and ApplicationsCatalytic Cross-Coupling Reactions