Synthesis of <i>N</i>-vinyl isothiocyanates and carbamates by the cleavage of NH-1,2,3-triazoles with one-carbon electrophiles
Vladimir Motornov, Petr Beier
Abstract
Metal-free cascade reaction of NH-1,2,3-triazoles with one-carbon electrophiles, such as thiophosgene and triphosgene, led to N -vinylated ring cleavage products.
Topics & Concepts
ChemistryElectrophileCleavage (geology)Carbon fibersOrganic chemistryCombinatorial chemistryMedicinal chemistryCatalysisEngineeringMaterials scienceGeotechnical engineeringComposite materialFracture (geology)Composite numberCyclopropane Reaction MechanismsFluorine in Organic ChemistrySynthesis and Catalytic Reactions