Na<sub>1.5</sub>Rb<sub>0.5</sub>PO<sub>3</sub>F·H<sub>2</sub>O: synthesis, properties, and stepwise reconstruction of the hydrogen bond network
Xinrui Yang, Xin Liu, Zujian Wang, Xue‐Bin Deng, Hejie Lu, Yujia Li, Xifa Long, Ling Chen, Li‐Ming Wu
Abstract
The precise substitution of NH 4 + with Na + /Rb + cations in NPF·H 2 O leads to a stepwise reconstruction of the hydrogen bond networks from NPF·H 2 O, NNPF·H 2 O to NRPF·H 2 O, giving rise to the symmetry and optical property tunings.
Topics & Concepts
Substitution (logic)CrystallographyHydrogen bondChemistryHydrogenMaterials scienceMoleculeComputer scienceOrganic chemistryProgramming languageCrystal Structures and PropertiesSolid-state spectroscopy and crystallographyLuminescence Properties of Advanced Materials