Chameleonic layered metal–organic frameworks with variable charge-ordered states triggered by temperature and guest molecules
Jian Chen, Yoshihiro Sekine, Atsushi Okazawa, Hiroyasu Sato, Wataru Kosaka, Hitoshi Miyasaka
Abstract
a solvation/desolvation process at room temperature. This example demonstrates a new multiple-switching system based on electron transfer and host-guest chemistry in a charge-flexible metal-organic framework.
Topics & Concepts
Charge (physics)Metal-organic frameworkMoleculeChemical physicsOrganic moleculesMetalVariable (mathematics)Charge orderingMaterials scienceComputational chemistryNanotechnologyChemistryPhysicsPhysical chemistryOrganic chemistryQuantum mechanicsMetallurgyMathematicsMathematical analysisAdsorptionMetal-Organic Frameworks: Synthesis and ApplicationsMagnetism in coordination complexesLanthanide and Transition Metal Complexes