Deprotonated diaminocarbene platinum complexes for thermoresponsive luminescent silicone materials: both catalysts and luminophores
Mikhail V. Dobrynin, Svetlana O. Kasatkina, Sergey V. Baykov, Polina Yu. Savko, Nikita S. Antonov, Alexander S. Mikherdov, Vadim P. Boyarskiy, Regina M. Islamova
Abstract
-methylhydrosiloxane) hydrosilylation cross-linking. Silicone rubbers obtained with (aminoisoquinoline)-containing complex 3d exhibit temperature-responsive luminescence. Their emission changes irreversibly when heated from 80-100 °C (green radiation) to 120 °C or more (blue radiation).
Topics & Concepts
HydrosilylationDeprotonationPlatinumLuminescenceSiliconeCatalysisPolymer chemistryMaterials scienceChelationPhotochemistryChemistryOrganic chemistryOptoelectronicsIonOrganic Light-Emitting Diodes ResearchN-Heterocyclic Carbenes in Organic and Inorganic ChemistryLuminescence and Fluorescent Materials