Electronic Control of Spin-Crossover Properties in Four-Coordinate Bis(formazanate) Iron(II) Complexes
Francesca Milocco, F. de Vries, Imke M. A. Bartels, Remco W. A. Havenith, Jordi Cirera, Serhiy Demeshko, Franc Meyer, Edwin Otten
Abstract
-substituent has a different influence depending on whether it is present at the C-Ar or N-Ar rings, which is ascribed to the opposing effect on metal-ligand σ- and π-bonding.
Topics & Concepts
ChemistrySpin crossoverCrossoverSpin (aerodynamics)CrystallographyThermodynamicsPhysicsComputer scienceArtificial intelligenceMagnetism in coordination complexesLanthanide and Transition Metal ComplexesMetal-Catalyzed Oxygenation Mechanisms