Ultra-stable K metal anode enabled by oxygen-rich carbon cloth
Yangyang Xie, Junxian Hu, Zexun Han, Hailin Fan, Jingyu Xu, Yanqing Lai, Zhian Zhang
Abstract
The K metal batteries are emerged as promising alternatives beyond commercialized Li-ion batteries. However, suppressing uncontrolled dendrite is crucial to the accomplishment of K metal batteries. Herein, an oxygen-rich treated carbon cloth (TCC) has been designed as the K plating host to guide K homogeneous nucleation and suppress the dendrite growth. Both density function theory calculations and experimental results demonstrate that abundant oxygen functional groups as K-philic sites on TCC can guide K nucleation and deposition homogeneously. As a result, the TCC electrode exhibits an ultra-long-life over 800 cycles at high current density of 3.0 mA·cm −2 for 3.0 mA·h·cm −2 . Furthermore, the symmetrical cells can run stably for 2,000 h with low over-potential less than 20 mV at 1.0 mA·cm −2 for 1.0 mA·h·cm −2 . Even at a higher current of 5.0 mA·cm −2 , the TCC electrode can still stably cycle for 1,400 h.