Effect of Membrane Orientation and Concentration of Draw Solution on the Behavior of Commercial Osmotic Membrane in a Novel Dynamic Forward Osmosis Tests
Du Bai, Boguslaw Kruczek
Abstract
Dynamic performance tests, commonly used to characterize gas separation membranes, are not utilized to characterize osmotic membranes. This paper demonstrates the application of a novel dynamic forward osmosis test to characterize a commercial osmotic membrane. In particular, we report the effect of membrane orientation (active layer draw solution (AL-DS) vs. active layer feed solution (AL-FS)) and the draw solution concentration on the membrane’s transient and steady-state behaviors. A step-change in the draw solution concentration initiated the dynamic test, and the mass and concentration of the feed and draw solutions were recorded in real-time. The progress of the experiments in two different membrane orientations is markedly different; also, the draw solution concertation has a different effect in the orientations. A positive salt time lag is observed in both orientations; however, the salt time lag in the AL-FS orientation (4.3−4.6 min) is practically independent of the draw solution concentration, but it increases from 7 to 20 min with the draw solution concertation in the AL-DS orientation. A negative water time lag, ranging from −11 to −20 min depending on the draw solution concentration, is observed in the AL-DS orientation. Still, in the AL-FS orientation, the water flux is practically constant from the experiment’s onset, leading to a negligible water time lag (<1 min). The new method demonstrated in this paper can be a potent tool for characterizing osmotic membranes.