Mono- and bis-Pd(<scp>ii</scp>) complexes of N-confused dithiahexaphyrin(1.1.1.1.1.0) with the absorption and aromaticity modulated by Pd(<scp>ii</scp>) coordination, macrocycle contraction and ancillary ligands
Meng Sun, Yongshu Xie, Glib Baryshnikov, Chengjie Li, Feng Sha, Xin‐Yan Wu, Hans Ågren, Shijun Li, Qizhao Li
Abstract
moiety. These complexes present tunable 26 π aromaticity and NIR absorption up to 1060 nm. This work provides an effective approach for developing distinctive porphyrinoid Pd(ii) complexes from a single porphyrinoid, without resorting to tedious syntheses of a series of porphyrinoid ligands.
Topics & Concepts
ChemistryContraction (grammar)StereochemistryAbsorption (acoustics)Medicinal chemistryMaterials scienceInternal medicineMedicineComposite materialPorphyrin and Phthalocyanine ChemistryLuminescence and Fluorescent MaterialsMolecular Sensors and Ion Detection