Diazaphosphinanes as hydride, hydrogen atom, proton or electron donors under transition-metal-free conditions: thermodynamics, kinetics, and synthetic applications
Jingjing Zhang, Jin‐Dong Yang, Jin‐Pei Cheng
Abstract
-butyl)-phenoxyl radical, implying a tunneling effect. Furthermore, successful applications of these diverse P-H bond energetic parameters in organic syntheses were exemplified, shedding light on more exploitations of these versatile and powerful diazaphosphinane reagents in organic chemistry.
Topics & Concepts
HydrideKineticsProtonHydrogen atomChemistryHydrogenTransition metalAtom (system on chip)ThermodynamicsPhysical chemistryMetalHydrogen storageComputational chemistryCatalysisOrganic chemistryPhysicsNuclear physicsComputer scienceAlkylQuantum mechanicsEmbedded systemAsymmetric Hydrogenation and CatalysisOrganometallic Complex Synthesis and CatalysisMetalloenzymes and iron-sulfur proteins