Planar Hypercoordinate Carbons in Alkali Metal Decorated CE<sub>3</sub><sup>2−</sup> and CE<sub>2</sub><sup>2−</sup> Dianions
Luis Leyva‐Parra, Luz Diego, Diego Inostroza, Osvaldo Yáñez, Rodolfo Pumachagua‐Huertas, Jorge Barroso, Alejandro Vásquez‐Espinal, Gabriel Merino, William Tiznado
Abstract
Abstract After exploring the potential energy surfaces of M m CE 2 p (E=S−Te, M=Li−Cs, m =2, 3 and p = m ‐2) and M n CE 3 q (E=S−Te, M=Li−Cs, n =1, 2, q = n ‐2) combinations, we introduce 38 new global minima containing a planar hypercoordinate carbon atom (24 with a planar tetracoordinate carbon and 14 with a planar pentacoordinate carbon). These exotic clusters result from the decoration of V‐shaped CE 2 2− and Y‐shaped CE 3 2− dianions, respectively, with alkali counterions. All these 38 systems fulfill the geometrical and electronic criteria to be considered as true planar hypercoordinate carbon systems. Chemical bonding analyses indicate that carbon is covalently bonded to chalcogens and ionically connected to alkali metals.