Ultrastrong Red Circularly Polarized Luminescence Promoted from Chiral Transfer and Intermolecular Förster Resonance Energy Transfer in Ternary Chiral Emissive Nematic Liquid Crystals
Kun Yao, Yihao Shen, Yang Li, Xiaojing Li, Yiwu Quan, Yixiang Cheng
Abstract
Chiral emissive liquid crystals (N*-LCs) have been proved to greatly amplify the circularly polarized luminescence (CPL) signals due to highly regular spiral arrangement of dyes in a well-organized liquid crystals system. Normally, CPL materials with a high luminescence dissymmetry factor (glum) and quantum yield (QY) can meet the real application requirement. Here, four chiral aggregate-induced emission (AIE) active donors (Guests A1–A4: R-C2, R-C4, R-C6, R-C8, chiral dopant, and energy donor) and achiral AIE-active acceptors (Guest B: PBCy, CPL emitter) were doped into the commercial nematic liquid crystals E7 (N-LCs, Host) to form CPL-active ternary chiral emissive N-LCs (T-N*-LCs), respectively. This kind of T-N*-LCs could emit strong red CPL with QY = 16.56% and glum up to 1.51 through intermolecular energy transfer and chirality induction from the supramolecular self-assembly of T-N*-LCs. This work provides the effective strategy for the development of high glum CPL materials.