Slow magnetic relaxation in a homoaxially phosphine oxide coordinated pentagonal bipyramidal Dy(<scp>iii</scp>) complex
Pankaj Kalita, Naushad Ahmed, Shruti Moorthy, Virginie Béreau, Arun Kumar Bar, Pawan Kumar, Prakash Nayak, Jean‐Pascal Sutter, Saurabh Kumar Singh, Vadapalli Chandrasekhar
Abstract
Synthesis, structural characterization and combined experimental and theoretical magnetic properties of a new homoaxially phosphine oxide coordinated pentagonal bipyramidal complex, [(L N 3 O 2 Ph )Dy III (Cy 3 PO) 2 ]·[BPh 4 ] are reported.
Topics & Concepts
Pentagonal bipyramidal molecular geometryPhosphine oxideCrystallographyChemistryBipyramidPhosphineRelaxation (psychology)Trigonal bipyramidal molecular geometryOxideMaterials scienceCrystal structureOrganic chemistryBiologyCatalysisNeuroscienceMagnetism in coordination complexesLanthanide and Transition Metal ComplexesMetal-Catalyzed Oxygenation Mechanisms