Litcius/Paper detail

Al<sup>3+</sup> Dopants Induced Mg<sup>2+</sup> Vacancies Stabilizing Single-Atom Cu Catalyst for Efficient Free-Radical Hydrophosphinylation of Alkenes

Qi Xu, Chenxi Guo, Beibei Li, Zedong Zhang, Yajun Qiu, Shubo Tian, Lirong Zheng, Lin Gu, Wensheng Yan, Dingsheng Wang, Jian Zhang

2022Journal of the American Chemical Society75 citationsDOI

Abstract

/MgO(Al) derives from the accelerated initiating step of phosphinoyl radical triggered by individual Cu atoms.

Topics & Concepts

DopantChemistryCatalysisSelectivityAtom (system on chip)Markovnikov's ruleHomogeneousDopingInorganic chemistryPhysical chemistryCrystallographyOrganic chemistryMaterials scienceThermodynamicsEmbedded systemComputer scienceRegioselectivityPhysicsOptoelectronicsAdvanced Photocatalysis TechniquesChemical Synthesis and CharacterizationNanocluster Synthesis and Applications