Efficient Production of Carbonyl Sulfide in the Low‐NO<sub>x</sub> Oxidation of Dimethyl Sulfide
Christopher M. Jernigan, Charles H. Fite, Luc Vereecken, Max Berkelhammer, Andrew W. Rollins, Pamela S. Rickly, Anna Novelli, Domenico Taraborrelli, Christopher D. Holmes, Timothy H. Bertram
Abstract
Abstract The oxidation of carbonyl sulfide (OCS) is the primary, continuous source of stratospheric sulfate aerosol particles, which can scatter shortwave radiation and catalyze heterogeneous reactions in the stratosphere. While it has been estimated that the oxidation of dimethyl sulfide (DMS), emitted from the surface ocean accounts for 8%–20% of the global OCS source, there is no existing DMS oxidation mechanism relevant to the marine atmosphere that is consistent with an OCS source of this magnitude. We describe new laboratory measurements and theoretical analyses of DMS oxidation that provide a mechanistic description for OCS production from hydroperoxymethyl thioformate, a ubiquitous, soluble DMS oxidation product. We incorporate this chemical mechanism into a global chemical transport model, showing that OCS production from DMS is a factor of 3 smaller than current estimates, displays a maximum in the tropics consistent with field observations and is sensitive to multiphase cloud chemistry.