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Activation of N<sub>2</sub>O and SO<sub>2</sub> by the P–B Bond System. Reversible Binding of SO<sub>2</sub> by the P–O–B Geminal Frustrated Lewis Pair

Natalia Szynkiewicz, Jarosław Chojnacki, Rafał Grubba

2020Inorganic Chemistry36 citationsDOIOpen Access PDF

Abstract

Herein, we present the first transformation of borylphosphine into borylphosphinite using nitrous oxide. Borylphosphine reacts with N2O via insertion of a single oxygen atom into the P–B bond and formation of a P–O–B bond system. Borylphosphine and borylphosphinite capture SO2 and activate it in an irreversible and reversible manner, respectively.

Topics & Concepts

ChemistryGeminalCrystallographyStereochemistryOrganoboron and organosilicon chemistrySynthesis and characterization of novel inorganic/organometallic compoundsChemical Synthesis and Reactions
Activation of N<sub>2</sub>O and SO<sub>2</sub> by the P–B Bond System. Reversible Binding of SO<sub>2</sub> by the P–O–B Geminal Frustrated Lewis Pair | Litcius