Ynamides in Free Radical Reactions
Capucine Mahe, Kevin Cariou
Abstract
Abstract In this review we present the transformations that have been developed with ynamides and free radicals. These reactions involve carbon‐, heteroatom‐ or even metalloid‐centered radicals and include inter‐ and intra‐molecular reactions. The scope and mechanism of these transformations are discussed in details, including the most recent examples relying on photoredox catalysis. magnified image
Topics & Concepts
ChemistryRadicalScope (computer science)HeteroatomPhotoredox catalysisCatalysisMechanism (biology)Free-radical reactionCombinatorial chemistryPhotochemistryOrganic chemistryEpistemologyComputer sciencePhotocatalysisRing (chemistry)PhilosophyProgramming languageCatalytic Alkyne ReactionsCyclopropane Reaction MechanismsCatalytic C–H Functionalization Methods