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Self-preservation Effect of Gas Hydrates

Аnatoliy Pavlenko

2021Rocznik Ochrona Środowiska11 citationsDOIOpen Access PDF

Abstract

This work was performed to improve the storage and transportation technology of gas hydrates in nonequilibrium conditions. At atmospheric pressure and positive ambient temperature, they gradually dissociate into gas and water. Simulation of the gas hydrate dissociation will determine optimal conditions for their transportation and storage, as well as minimize gas loss. Thermodynamic parameters of adiabatic processes of forced preservation of pre-cooled gas hydrate blocks with ice layer were determined theoretically and experimentally. Physical and mathematical models of these processes were proposed. The scientific novelty is in establishing quantitative characteristics that describe the gas hydrates thermophysical parameters thermophysical characteristics influence on the heat transfer processes intensity on the interphase surface under conditions of gas hydrates dissociation. Based on the results of experimental studies, approximation dependences for determining the temperature in the depths of a dissociating gas hydrate array have been obtained. Gas hydrates dissociation mathematical model is presented.

Topics & Concepts

Clathrate hydrateAdiabatic processDissociation (chemistry)HydrateThermodynamicsChemistryNon-equilibrium thermodynamicsHeat transferIsothermal processPhysical chemistryOrganic chemistryPhysicsMethane Hydrates and Related PhenomenaSpacecraft and Cryogenic TechnologiesMining and Gasification Technologies
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