Synthesis, characterization and redox properties of Ar–C=N→Ge←N=C–Ar containing system
I. V. Krylova, Evgeniya A. Saverina, Stanislav S. Rynin, Andrey V. Lalov, Mikhail E. Minyaev, Elena N. Nikolaevskaya, Mikhail A. Syroeshkin, Mikhail P. Egorov
Abstract
New Schiff base germanate derivative containing the chain Ar–C=N→Ge←N=C–Ar was synthesized and characterized by physical methods including X-ray diffraction. The stability of the corresponding radical anion obtained electrochemically was confirmed by cyclic voltammetry, the results were compared with UV-VIS data and quantum chemical calculations.
Topics & Concepts
ChemistryCyclic voltammetryGermanateQuantum chemicalRedoxDerivative (finance)IonDiffractionSchiff baseCharacterization (materials science)ElectrochemistryCrystallographyInorganic chemistryPhysical chemistryMoleculeOrganic chemistryNanotechnologyElectrodeEconomicsFinancial economicsMaterials sciencePhysicsOpticsSynthesis and characterization of novel inorganic/organometallic compoundsOrganometallic Complex Synthesis and CatalysisCrystallography and molecular interactions