Iron-catalyzed cross-electrophile coupling of bromostyrenes and chlorosilanes
Ying‐Chih Lin, Liang Zou, Renren Bai, Xiang‐Yang Ye, Tian Xie, Yang Ye
Abstract
An efficient Fe-catalyzed cross-electrophile vinyl silylation protocol is reported for the first time. A set of 1,4-diene silanes are conveniently synthesized from simple vinyl chlorosilanes and alkenyl bromides under mild reductive conditions.
Topics & Concepts
ElectrophileChemistrySilanesSilylationCatalysisOrganic chemistryCoupling (piping)Combinatorial chemistrySilaneMetallurgyMaterials scienceCatalytic Cross-Coupling ReactionsOrganoboron and organosilicon chemistryCatalytic C–H Functionalization Methods