Atomically accurate site-specific ligand tailoring of highly acid- and alkali-resistant Ti(<scp>iv</scp>)-based metallamacrocycle for enhanced CO<sub>2</sub> photoreduction
Yi-Qi Tian, Lin-Fang Dai, Wen-Lei Mu, Wei‐Dong Yu, Jun Yan, Chao Liu
Abstract
. This study serves as a striking testament to the latent potential of precision-guided surface ligand manipulation within robust clusters, while also underpinning a platform for producing microporous materials endowed with a myriad of surface functionalities.
Topics & Concepts
Alkali metalMicroporous materialLigand (biochemistry)CarboxylateChemistryAnataseCluster (spacecraft)TransferabilityMaterials scienceNanotechnologyPhotocatalysisCombinatorial chemistryStereochemistryOrganic chemistryCatalysisComputer scienceProgramming languageBiochemistryReceptorLogitMachine learningAdvanced Photocatalysis TechniquesMetal-Organic Frameworks: Synthesis and ApplicationsNanocluster Synthesis and Applications