Intermolecular dearomative [4 + 2] cycloaddition of naphthalenes <i>via</i> visible-light energy-transfer-catalysis
Pramod Rai, Kakoli Maji, Sayan K. Jana, Biplab Maji
Abstract
-selectivities. The late-stage modification of the derivatives of pharmaceutical agents further demonstrated the broad potentiality of this methodology. The efficacy of the introduced methods was further highlighted by the post-synthetic diversification of the products. Furthermore, photoluminescence, electrochemical, kinetic, control experiments, and density-functional theory calculations support energy-transfer catalysis.
Topics & Concepts
CycloadditionIntermolecular forceCatalysisChemistryNaphthaleneDensity functional theoryMoleculeReactivity (psychology)Combinatorial chemistrySelectivityComputational chemistryPhotochemistryOrganic chemistryMedicinePathologyAlternative medicineRadical Photochemical ReactionsCatalytic C–H Functionalization MethodsSulfur-Based Synthesis Techniques