Domino assembly of dithiocarbamates<i>via</i>Cu-catalyzed denitrogenative thiolation of iodotriazole-based diazo precursors
Yury N. Kotovshchikov, Rinat H. Sultanov, Gennadij V. Latyshev, Nikolay V. Lukashev, I. P. Beletskaya
Abstract
An efficient domino approach to assemble benzoxazoles and anthranilamides bearing dithiocarbamate moieties via a Cu-catalyzed three-component reaction between readily available 5-iodo-1,2,3-triazoles, amines, and CS 2 has been developed.
Topics & Concepts
DominoDiazoDithiocarbamateCatalysisCombinatorial chemistryChemistryCascade reactionComponent (thermodynamics)Organic chemistryThermodynamicsPhysicsCyclopropane Reaction MechanismsSulfur-Based Synthesis TechniquesSynthesis and Catalytic Reactions