Structure–function correlation of mononuclear nonheme copper(<scp>ii</scp>) compounds based on a ligand backbone effect and phenoxazinone synthase activity
Sarvesh S. Harmalkar, Vishnu R. Chari, R.K. Kunkalekar, Sunder N. Dhuri
Abstract
Mononuclear nonheme Cu( ii ) compounds 1 and 2 were synthesized and characterized by elemental analysis, ESI-MS, EPR, and single-crystal X-ray diffractrometry.
Topics & Concepts
ChemistryCopperLigand (biochemistry)Electron paramagnetic resonancePeripheral blood mononuclear cellSingle crystalStereochemistryCrystallographyOrganic chemistryBiochemistryReceptorNuclear magnetic resonanceIn vitroPhysicsMetal complexes synthesis and propertiesMetal-Catalyzed Oxygenation MechanismsMagnetism in coordination complexes