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Rational design of ZSM-5 zeolite containing a high concentration of single Fe sites capable of catalyzing the partial oxidation of methane with high turnover frequency

Akira Oda, Koshiro Aono, Naoya Murata, Kazumasa Murata, Masazumi Yasumoto, Nao Tsunoji, Kyoichi Sawabe, Atsushi Satsuma

2021Catalysis Science & Technology27 citationsDOI

Abstract

We successfully synthesized a Fe/ZSM-5 catalyst enabling conversion of methane to C1 oxygenates in record yields, and demonstrated that the fraction of the single Fe cation, as well as the Al distribution, are the powerful activity descriptors.

Topics & Concepts

CatalysisOxygenateMethaneZeoliteRational designZSM-5ChemistryFraction (chemistry)Turnover numberAnaerobic oxidation of methaneHydrocarbonChemical engineeringInorganic chemistryCombinatorial chemistryOrganic chemistryMaterials scienceNanotechnologyEngineeringCatalytic Processes in Materials ScienceCatalysis and Oxidation ReactionsZeolite Catalysis and Synthesis
Rational design of ZSM-5 zeolite containing a high concentration of single Fe sites capable of catalyzing the partial oxidation of methane with high turnover frequency | Litcius