New Access to Six‐Membered Phosphacycle Annulated Polyaromatic Ring System
Erbing Si, Peng Zhao, Lili Wang, Zheng Duan, François Mathey
Abstract
A facile Ag‐catalyzed intramolecular C–P bond formation reaction from easily accessible phosphine oxides has been developed. Several new heteroatoms fused π‐conjugated molecules were synthesized from this procedure with their structures confirmed by X‐ray structure analyses.
Topics & Concepts
ChemistryIntramolecular forceHeteroatomRing (chemistry)Conjugated systemMoleculePhosphineStereochemistryCombinatorial chemistryCatalysisOrganic chemistryPolymerAsymmetric Hydrogenation and CatalysisAsymmetric Synthesis and CatalysisCatalytic C–H Functionalization Methods