MOF-derived CeO<sub>2</sub> catalysts with Pr doping: engineering oxygen vacancies for improved CO<sub>2</sub> conversion to dimethyl carbonate
Jungseob So, Min Hye Jeong, Jungwon Yun, Bo An, Seung-Ik Kim, Geun-yeong Kim, Hyun‐Tak Kim, Tae Sun Chang, Jin Hee Lee, Iljeong Heo, Jinjoo An, Young‐Woo You, Minkyu Kim, Young Jin Kim
Abstract
Pr-doped CeO 2 from MOF templates exhibits enhanced catalytic performance for dimethyl carbonate synthesis from CO 2 and methanol, driven by increased oxygen vacancies and improved acidic/basic properties.
Topics & Concepts
DopingCatalysisOxygenCarbonateMaterials scienceDimethyl carbonateChemical engineeringOxygen evolutionInorganic chemistryChemistryPhysical chemistryMetallurgyOptoelectronicsOrganic chemistryEngineeringElectrochemistryElectrodeCarbon dioxide utilization in catalysisCatalytic Processes in Materials ScienceCatalysts for Methane Reforming