One-pot, three-component regioselective coupling reaction of triphenylamine/carbazole derivatives with [60]fullerene and indoles <i>via</i> an “umpolung relay” strategy
Xinrui Chen, Qianwen Zhang, Ge-Ge Tao, Jun Xuan, Hongping Zhou, Yupeng Tian, Fei Li
Abstract
An “umpolung relay” three-component regioselective coupling reaction of triphenylamine/carbazole derivatives with C 60 and indoles was developed, which features high regioselectivity, broad substrate scope, and excellent functional group tolerance.
Topics & Concepts
RegioselectivityUmpolungTriphenylamineCarbazoleChemistryTryptamineFunctional groupSubstrate (aquarium)Combinatorial chemistryFullereneCoupling (piping)Organic chemistryPhotochemistryCatalysisMaterials scienceNucleophileBiochemistryOceanographyGeologyPolymerMetallurgyFullerene Chemistry and ApplicationsSynthesis and Properties of Aromatic CompoundsCarbon Nanotubes in Composites