Unravelling the water adsorption in a robust iron carboxylate metal–organic framework
Dirk Lenzen, Jakob G. Eggebrecht, Paulo G. M. Mileo, Dominik Fröhlich, Stefan K. Henninger, Cesare Atzori, Francesca Bonino, Alexandra Lieb, Guillaume Maurin, Norbert Stock
Abstract
A Fe-MOF was obtained from aqueous solution in high yield under reflux. The water sorption properties were studied by powder X-ray diffraction, volumetric and gravimetric sorption experiments and molecular simulations. The subsequent filling of hydrophobic and hydrophilic pores as well as the stability of the material are demonstrated.
Topics & Concepts
CarboxylateAdsorptionMetal-organic frameworkMetalChemistryInorganic chemistryChemical engineeringEnvironmental chemistryOrganic chemistryEngineeringMetal-Organic Frameworks: Synthesis and ApplicationsEnhanced Oil Recovery TechniquesNMR spectroscopy and applications