A sustainable approach to dairy wastewater treatment through electrocoagulation: From beverage cans to clean water
N. Idusuyi, Marzouq Adeyemi Adebayo, Chinenye Adaobi Igwegbe, Thomas Aghogho Orhadahwe, Anina James, Rasaq A. Kazeem
Abstract
• The raw dairy wastewater had COD, BOD, and turbidity of 1032 mg/L, 420 mg/L and 5.26 NTU suggesting the presence of organic and inorganic substances. • EC at 20 V and pH 9 performed for 15 min, exhibited a significant decrease in COD from 1032 mg/L to 86 mg/L, achieving a 91.67% removal rate. • From Taguchi analysis pH emerged as the most critical factor affecting BOD, with a broader S/N ratio range of 38.31 – 38.74 • From Taguchi analysis, voltage emerged as the most influencing factor in optimizing turbidity reduction, with an S/N ratio range of 17.09 – 25.63. • Using TOPSIS the best combinations of experimental runs for electrocoagulation can be arranged as Exp 7 > Exp 6 > Exp 9 > Exp 8 > Exp 5 > Exp 2 > Exp 3 > Exp 4 > Exp 1. Dairy industry wastewater, laden with high levels of biological oxygen demand (BOD), chemical oxygen demand (COD), and various pollutants, poses significant environmental concerns. This study introduces the innovative use of recycled aluminium cans as electrodes for electrocoagulation, presenting an eco-friendly and cost-effective approach to wastewater treatment that aligns with circular economy principles. This study explores the efficacy of electrocoagulation (EC) in treating dairy wastewater, focusing on the influence of treatment duration, voltage, and pH levels on BOD, COD, and turbidity reduction. Utilizing recycled aluminium electrodes derived from beverage cans, a Taguchi design of experiments with a 3-factor, 3-level orthogonal array was employed. Results from nine experiments reveal that higher voltages and alkaline pH levels notably enhanced COD and BOD removal efficiencies. For instance, high removal rates of 91.67 % for COD and 95.36 % for BOD were achieved at 20 V and pH 9 over a 15-minute treatment duration were obtained from experiments. Furthermore, optimal overall EC performance parameters were obtained using Taguchi and Multi-response optimization using TOPSIS. Analysis of turbidity removal efficiencies demonstrates the significant impact of voltage and treatment duration. The study provides valuable insights into optimizing electrocoagulation processes for efficient treatment of dairy wastewater, offering a sustainable solution for environmental preservation and resource recovery.