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On the factors influencing the chiroptical response of conjugated polymer thin films

Beth A. Laidlaw, Julien Eng, Jessica Wade, Xingyuan Shi, Francesco Salerno, Matthew J. Fuchter, Thomas J. Penfold

2021Chemical Communications25 citationsDOIOpen Access PDF

Abstract

-benzothiadiazole) (F8BT). We reveal the significance of electric-magnetic coupling, at both short (molecular-level) and intermediate (delocalised over multiple polymer chains) length scales, on the magnitude of the dissymmetry. These findings provide a framework for the design of new materials with an enhanced chiroptical response.

Topics & Concepts

FluoreneConjugated systemPolymerMaterials scienceCoupling (piping)Chemical physicsOptoelectronicsChemistryComposite materialLiquid Crystal Research AdvancementsPhotoreceptor and optogenetics researchMolecular spectroscopy and chirality
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