Phosphinoindenyl and phosphazidoindenyl complexes of lanthanum and samarium: synthesis, characterisation, and hydroamination catalysis
Matthias Steiner, Johann Hlina, Johanna M. Uher, Roland C. Fischer, Dmytro Neshchadin, Theresa Wilfling
Abstract
, Ln = La (3-La), Sm (3-Sm), respectively. The five complexes catalyse the intramolecular hydroamination/cyclisation of 2,2-diphenylpent-4-ene-1-amine using 2% catalyst loading. All compounds were characterised by NMR and UV-Vis spectroscopy, single-crystal X-ray diffraction, and elemental analysis and DFT calculations were performed for 3-La.
Topics & Concepts
HydroaminationLanthanumSamariumCatalysisChemistryRare earthMetalOrganic chemistryCombinatorial chemistryMineralogyOrganometallic Complex Synthesis and CatalysisMetal complexes synthesis and propertiesLanthanide and Transition Metal Complexes