Hydrogen Atom Transfer Thermodynamics of Homologous Co(III)- and Mn(III)-Superoxo Complexes: The Effect of the Metal Spin State
Yao‐Cheng Tian, Yang Jiang, Yen‐Hao Lin, Peng Zhang, Chun‐Chieh Wang, Shengfa Ye, Way‐Zen Lee
Abstract
center. The present work underscores the role of the metal spin state being as crucial as the oxidation state in modulating BDFEs.
Topics & Concepts
ChemistryMetalAdductOxidation stateHydrogen atomElectron transferBond cleavageSpin statesBond-dissociation energyPhysical chemistryAtom (system on chip)ManganeseCrystallographyCatalysisDissociation (chemistry)Computational chemistryInorganic chemistryOrganic chemistryComputer scienceAlkylEmbedded systemMetal-Catalyzed Oxygenation MechanismsFree Radicals and AntioxidantsElectrocatalysts for Energy Conversion