Metal–Organic Frameworks Based on a Janus-Head Biquinoline Ligand as Catalysts in the Transformation of Carbonyl Compounds into Cyanohydrins and Alcohols
Juana M. Pérez, Samuel Morales-Cámara, Francisco M. García-Salas, Noelia Ruiz-Cuevas, Mireya E. López‐Vargas, Duane Choquesillo‐Lazarte, Javier Cepeda, José A. Fuentes, Víctor Karim Abdelkader-Fernández, Antonio Rodríguez‐Diéguez, Sara Rojas, Ignacio Fernández
Abstract
provided the highest efficiency ever reported in the MOF-catalyzed cyanosilylation of carbonyl compounds by using only 0.5 mol % of catalyst loading, room temperature, and solvent-free conditions. Furthermore, the hydroboration of ketones has been reported for the first time with this type of s-block metal catalysts obtaining from moderate to good conversions.
Topics & Concepts
ChemistryCatalysisMetal-organic frameworkHydroborationLigand (biochemistry)Infrared spectroscopyThermogravimetric analysisSBusTrimesic acidCrystallographyOrganic chemistryMoleculeBiochemistryReceptorAdsorptionMetal-Organic Frameworks: Synthesis and ApplicationsChemical Synthesis and ReactionsCarbon dioxide utilization in catalysis